DEPOLYMERIZATION AND KINETICS OF DEPOLYMERIZATION OF POLYETHYLENE TEREPHTHALATE USING DIBUTYLTIN OXI

Depolymerization of poly(ethylene terephthalate) (PET) was performed in the tubular bomb microreactor which contained the solution of PET in methanol and dibutyltin oxide at the temperature ranging from 433 K to 473 K, the reaction time from 5 to 45 min and the catalyst-to-PET ratio of 0.3%-2% by weight. The optimal condition for PET depolymerization catalyzed by dibutyltin oxide is the temperature of 443-453 K, the reaction time of 20-25 min and 0.8% by weight of catalyst. By using differential methods, the activation energy for the depolymerization process was found to be 154.05 k J/mol in the temperature range from 433-463 K.