A Sterically Hindered Zirconocene Complex (1,2-Ph2C5H3)2ZrCl2:Synthesis, Structure and Properties as

期刊名字：中国化学快报（英文版）
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论文作者：Fan ZHANG，Ying MU，Yue Tao ZHAN
作者单位：Department of Chemistry,Institute of Chemistry
更新时间：2022-12-13
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论文简介

An unbridged zirconocene complex bis(1,2-diphenylcyclopentadienyl)zirconium dichloride [(1,2-Ph2-C5H3)2ZrCl2] 1 has been synthesized and structurally characterized. When activated by MAO, 1 produces ultra-high molecular weight polyethylene with high melting transition temperature, as well as atactic oligopropylene with average molecular weight of ～1150 g mol-1.

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A Sterically Hindered Zirconocene Complex (1,2-Ph2C5H3)2ZrCl2:Synthesis, Structure and Properties as

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