Effects of WOx modification on the activity, adsorption and redox properties of CeO2 catalyst for NO

A series of WO3/CeO2 (WOx/CeO2) catalysts were synthesized by wet impregnation of ammonium metatungstate on a CeO2 support.The resulting solid acid catalysts were characterized by X-ray diffraction (XRD),UV-Vis spectroscopy (UV-Vis),Raman spectroscopy (Raman),in-situ Fourier transform infrared spectroscopy (in-situ FT-IR) of ammonia adsorption,NH3-TPD,H2 temperatureprogrammed reduction (H2-TPR),NH3/NO oxidation and activity measurements for NOx reduction by NH3 (NH3-SCR).The results show that polytungstate (WOx) species are the main species of tungsten oxide on the surface of ceria.The addition of tungsten oxide enhances the Br(ō)nsted acidity of ceria catalysts remarkably and decreases the amount of surface oxygen on ceria,with strong interaction between CeO2 and WOx.As a result,the N2 selectivity of NH3 oxidation and NH3-SCR at high temperatures (＞ 300℃) is enhanced.Therefore,a wide working temperature window in which NOx conversion exceeds 80％ (NOx conversion ＞ 80％) from 200 to 450℃,is achieved over 10 wt.％ WOx/CeO2 catalyst.A tentative model of the NH3-SCR reaction route on WOx/CeO2 catalysts is presented.