Simulation of Whole Periodic Operation of Naphtha Pyrolysis

A simulation strategy based on a simplified Lobo-Evans zone method for a radiant box and an approach for the local pressure-drop along the reaction tube in an industrial cracking furnace was established. A rigorous approach including a set of molecular reactions, radiation and coke formation models was used to simulate the naphtha pyrolysis in the cracking furnace. The simulation predicted the periodic operating state of the cracking furnace. The profiles of main product yields, coke layer thickness, tube skin temperature, and other operation parameters were studied with respect to time. The simulation showed that the calculated results were in good agreement with the real working plant experience.