合成气甲烷化制天然气通过鉴定 合成气甲烷化制天然气通过鉴定

合成气甲烷化制天然气通过鉴定

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800·化工进展2012年第31卷[31] Dumesic J A, Roman-Leshkov Y. Solvent effects on fructose383:149-155.dehydration to 5-hydroxymethylfurfural in biphasic systems saturated [44] Qi W, Huang R L, Su R X, et al. Syntheses of 5-hydroxymethylwith inorganic salts[J]. Top. Catal., 2009, 52: 297-303furfural and levoglucosan by selective dehydration of glucose using[32] Davis M E, Nikolla E N E, Roman-Leshkov Y, et al. One-potsolid acid and base catalysts [J]. Chem. Commum., 2010, 46ynthesis of 5-(hydroxymethyl) furfural from carbohydrates usingl115-1117ta zeolite []. ACS Catal, 2011, 1: 408-410[45] Watanabe M, Aizawa Y, lida T, et al. Catalytic glucose and fructose33] Mizuno N, Yamaguchi K, Sakurada T. Tin-tungsten mixed oxide asconversions with TiO and ZrO2 in water at 473 K: Relationshipefficient heterogeneous catalyst for conversion of saccharides to furanbetween reactivity and acid-base property determined by TPDmeasurement [ J]. AppL. Catal. A: Gen, 2005, 295: 150-156[34] Hansen T S, Mielby J, Riisager A Synergy of boric acid and added [46] Watanabe M, Qi X H, Aida T M, et al. Catalytical conversion ofsalts in the catalytic dehydration of hexoses tofructose and glucose into 5-hydroxymethylfurfural in hot compressed5-hydroxymethylfurfural in water [] Green Chem., 2011, 13water by microwave heating [. Catal. Commun., 2008, 909-142244-2249[35] Yu H B, Wang P, Zhan S H, et al. Catalytic hydrolysis of [47] Yan HP, Yang Y, Tong D M, et al. Catalytic conversion of glucoselignocellulosic biomass into 5-hydroxymethylfurfural in ionic liquidto 5-hydroxymethylfurfural over SO4/ZrO2 and SO4"/ZrO2-Al2O3[]. Bioresou; Technol.,2011,102:4179-4183solid acid catalysts []. Catal. Comm[36] Hu S Q, Zhang Z F, Song J L, et al. Efficient conversion of glucose [48] Valente AA, Lima S, Dias AS, et al. Isomerization of D-glucose tohydroxymethylfurfural catalyzed by a common Lewis acidD-fructose over metallosilicate solid bases []. Appl CataL. A: GenSnCI(4)in an ionic liquid []. Green Chem., 2009, 11: 1746-17492008,339:21-27[37] Chung C H, Chun J A, Lee J w, et al. Catalytic production of[491 Ebitani K, Takagaki A, Ohara M, et al. A one-pot reaction for1-methyl-3-biorefinery: Combination of solid acid and base catalysts for directctylimidazolium chloride ionic liquid [] Korean J. Chem. Engproduction of 5-hydroxymethylfurfural from saccharides[J]. Chem2010,27:930-935Commun,2009,(41),6276-6278[38] Fang Z J, Zheng B H, Cheng J, et al. Microwave-assisted comversion [50] Christensen C H, Taarning E, Saravanamurugan S, et al. Zeolite-of carbohydrates into 5-hydroxymethylfurfural catalyzed by ZnClJ]catalyzed isomerization of triose sugars []. Chem. Sus. Chem, 2009aturforsch, B: Chem. Sci., 2010, 65: 168-172.625-627[39] Heeres H J, Rasrendra C B, Makertihartha IG B N, et al. Green[51] Davis M E, Moliner M, Roman-Leshkov Y P. Tin-containing zeoliteschemicals from D-glucose: Systematic studies on catalytic effects ofare highly active catalysts for the isomerization of glucose in water [1Its on the chemoselectivity and yield in aqueousNatl. Acad. Sci USA, 2010, 107: 6164-61csolutions [J]. Top. Ce2010,53:1241-1247[ 52] Hansen T S, Mielby J, Riisager A Synergy of boric acid and added[40] Pijnenburg H C M, Kuster B F M, Vanderbaan H S SinIts in the catalytic dehydration of hexoses toisomerization and hydrogenation of glucose in alkali solutions[J]5-hydroxymethylfurfural in water []. Green Chem., 2011, 13:Starke,1978,30:199205109-11[41]Beenackers J A W M, Kuster B F M, Vanderbaan H S. Physica53 Du Y G, Yang F L, Liu Q S, et al. Conversion of biomass into5-hydroxymethylfurfural using solid acid catalyst [J]. Bioresourof hexoses [J]. Appl. CataL., 1985, 16: 75-87.Techno.,2011,102:3424-3429[42] Lecomte J, Finiels A, Moreau C. Kinetic study of the isomerization of [54] Wang X H, Zhao QA, Wang L, ct al. High selective production ofglucose into fructose in the presence of anion-modified hydrotalcites5-hydroymethylfurfural from fructose by a solid heteropolyacid[ Starch- Starke,2002,54:75-7[43] Ebitani K, Ohara M, Takagaki A, et al. Syntheses of 5-hydroxy- [55] Wang X H, Fan CY, Guan H Y, et al. Conversion of fructose andmethylfurfural and levoglucosan by selective dehydration of glucoseusing solid acid and base catalysts []. AppL. Catal. A: Gen, 2010heteropolyacid salt [] Biomass Bioenergy, 2011. 35: 2659-2665技术信息合成气甲烷化制天然气通过鉴定研发了系列甲烷催化燃烧整体结构催化剂并进行了工程放2月21日,中国科学院大连化学物理研究所承担的国大,在低浓度甲烷流向换工共系统集成方面取得了显著进家863计划项目——合成气甲烷化制天然气通过了专家验展,申请发中国煤化工收。专家称,该成果有望成为替代国外甲烷化催化剂和工艺大连化CNMHG甲烷化催化剂研制的技术。及放大生产、甲烷化反应器及其工艺设计,以及多段循环甲据悉,研究组针对中低甲烷浓度煤层气的治理与利用,烷化工艺集成等关键核心技术方面取得了实质性进展。

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