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In Situ IR Spectroscopic Study on the Hydrogenation of 1,3-Butadiene on Fresh Mo2C/γ-Al2O3 Catalyst In Situ IR Spectroscopic Study on the Hydrogenation of 1,3-Butadiene on Fresh Mo2C/γ-Al2O3 Catalyst

In Situ IR Spectroscopic Study on the Hydrogenation of 1,3-Butadiene on Fresh Mo2C/γ-Al2O3 Catalyst

  • 期刊名字：中国炼油与石油化工（英文版）
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  • 论文作者：Zhang Jing，Wu Weicheng，Liu Shi
  • 作者单位：Liaoning Shihua University,SIN0PEC Tianjin Branch
  • 更新时间：2022-12-13
  • 下载次数：次
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论文简介

The surface species formed from the adsorption of 1,3-butadiene and 1,3-butadiene hydrogenation over the fresh Mo2C/γ-Al2O3 catalyst was studied by in situ IR spectroscopy. It is found that 1,3-butadiene adsorption on the Mo2C/γ-Al2O3 catalyst mainly formsπ-adsorbed butadiene (πs andπd) andσ-bonded surface species. These species are adsorbed mainly on the surface Moδ+(0

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