Effect of Polymerization Temperature on Propylene Polymerization with Cs-symmetric Metallocene Catal Effect of Polymerization Temperature on Propylene Polymerization with Cs-symmetric Metallocene Catal

Effect of Polymerization Temperature on Propylene Polymerization with Cs-symmetric Metallocene Catal

  • 期刊名字:中国化学快报(英文版)
  • 文件大小:
  • 论文作者:Zhi Qiang FAN,Tariq YASIN,Lin
  • 作者单位:Department of Polymer Science and Engineering
  • 更新时间:2022-12-12
  • 下载次数:
论文简介

A novel highly active Cs-symmetric metallocene catalyst namely: meso-dimethylsilylbis (2,4,6-trimethyl-1-indenyl)zirconium dichloride is presented. The effect of polymerization temperature (0-70 °C ) on the catalyst performance for propylene polymerization has been investigated. This catalyst shows very high activity at 50 ° C which is higher than the activity of the racemic analogue, and the resulted polypropylene is amorphous in nature with isotactic pentad content [mmmm] of 12 %.

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